Mechanistic Study of Ruthenium-Catalyzed C–H Hydroxylation Reveals an Unexpected Pathway for Catalyst Arrest

James B. C. Mack, Katherine L. Walker, Sophia G. Robinson, Richard N. Zare, Matthew S. Sigman, Robert M. Waymouth, and J. Du Bois

J. Am. Chem. Soc.,
2019, 141 (2), 972–980; DOI:10.1021/jacs.8b10950